Question

Freezing Point of Water | Temperature, Equation & Examples

Answer

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The freezing point of pure water at standard pressure (1 atm) is 0°C (32°F or 273.15 K).

Explanation

Water freezes at 0°C under 1 atmosphere of pressure. That temperature can change if pressure or dissolved solutes change — common effects are freezing-point depression by solutes and slight melting-point change with pressure. The triple point of water (where solid, liquid, and vapor coexist) is at $0.01^\circ\text{C}$ and $611.657\text{ Pa}$.

Key equations

  • Celsius ↔ Fahrenheit:

$T(^{\circ}\text{F})=\dfrac{9}{5}T(^{\circ}\text{C})+32$

  • Celsius ↔ Kelvin:

$T(\text{K})=T(^{\circ}\text{C})+273.15$

  • Freezing-point depression (colligative property) for a dilute solution:

$$\Delta T_f = i\,K_f\,m$$
where $i$ is the van ‘t Hoff factor (number of particles per formula unit), $K_f$ is the cryoscopic constant ($1.86^\circ\text{C}\cdot\text{kg}\cdot\text{mol}^{-1}$ for water), and $m$ is the molality (mol solute per kg solvent).

  • Pressure dependence of melting/freezing (Clausius–Clapeyron form):

$$\frac{dP}{dT}=\frac{\Delta H_{\text{fus}}}{T\,\Delta V}$$
For ice/water this gives an approximate slope of about $-0.0074^\circ\text{C}$ per atm (melting point falls slightly with increasing pressure).

Examples (step-by-step)

1) Convert the freezing point to Fahrenheit and Kelvin.

  • Celsius value: $0^\circ\text{C}$.
  • Fahrenheit:

$$T(^{\circ}\text{F})=\frac{9}{5}\cdot 0 + 32 = 32^\circ\text{F}$$

  • Kelvin:

$$T(\text{K})=0 + 273.15 = 273.15\text{ K}$$

2) Freezing-point depression for 1.00 molal NaCl (approximate; NaCl $\to$ Na$^+$ + Cl$^-$ so $i\approx 2$).

  • Use $\Delta T_f = i K_f m$:

$$\Delta T_f = 2 \times 1.86^\circ\text{C}\cdot\text{kg}\cdot\text{mol}^{-1} \times 1.00\text{ m} = 3.72^\circ\text{C}$$

  • New freezing point:

$$0^\circ\text{C} – 3.72^\circ\text{C} = -3.72^\circ\text{C}$$
(Real solutions deviate from ideality; $i$ and activity effects adjust the result.)

3) Pressure effect (qualitative):

  • Increasing pressure by 100 atm would lower freezing point by roughly $100 \times 0.0074^\circ\text{C} \approx 0.74^\circ\text{C}$ (approximate).

Important notes

  • Pure water can supercool below $0^\circ\text{C}$ and remain liquid if undisturbed or free of nucleation sites.
  • Impurities (salts, alcohols, sugars) lower the freezing point; this is why salt melts ice on roads.
  • The triple point at $0.01^\circ\text{C}$ is used to define the Kelvin temperature scale precisely.

If you want, I can: (a) compute freezing-point depression for a specific solution (type and concentration), (b) show a derivation of the Clausius–Clapeyron relation for solid–liquid equilibrium, or (c) give experimental examples of supercooling. Which would you like?